Respuesta :
Answer:
Freezing point of the solution = -120.02 °C
Explanation:
When a non-volatile solute is added in a volatile solvent, then vapour pressure of the pure solvent will decrease which results in depression in freezing point.
Molal freezing point depression constant for ethanol = 2.0 °C/m
[tex]\Delta T_f = K_f \times m[/tex]
Where,
[tex]\Delta T_f[/tex] = Depression in freezing point
[tex]K_f[/tex] = Molal freezing point depression constant
m = Molality
[tex]m = \frac{Mass of solute in g}{Molecular mass of solute\times Mass of solvent in Kg}[/tex]
Mass of glycerin (Solute) = 50.0 g
Molecular mass of glycerin = 92.09
Mass of ethanol (Solvent) = 200 g = 0.200 Kg
[tex]m = \frac{50.0}{92.09 \times 0.200}[/tex]
m = 2.71
Now, put the value of molality, molal freezing point depression constant in the formula,
[tex]\Delta T_f = K_f \times m[/tex]
[tex]\Delta T_f = 2.00 \times 2.71[/tex]= 5.42 °C
Freezing point of solvent - freezing point of solution = ΔTf
-114.6 °C - freezing point of solution = 5.42 °C
freezing point of solution = -5.42 - 114.6
= -120.02 °C
The Freezing point of the solution is -120.02 °C
Calculation of freezing point:
But first molarity should be determined
Since
Mass of glycerin (Solute) = 50.0 g
The molecular mass of glycerin = 92.09
Mass of ethanol (Solvent) = 200 g = 0.200 Kg
So, molarity should be
[tex]= 50 \div (92.09 \times 0.200)[/tex]
= 2.71
Now freezing point should be
[tex]= (2.00 \times 2.71) - 114.60[/tex]
= 5.42 - 114.60
= -120.02°C
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