Answer: Option (4) is the correct answer.
Explanation:
According to the reactivity series, a more reactive metal has the ability to replace a less reactive metal in a chemical reaction.
It is known that calcium is more reactive than magnesium. So, in a chemical reaction magnesium can never replace calcium.
For example, [tex]Mg(s) + Ca(OH)_2(aq) \rightarrow Ca(s) + Mg(OH)_2(aq)[/tex]
Therefore, this given reaction is not possible. But rest all given reactions are possible.
Thus, we can conclude that out of the given options [tex]Mg(s) + Ca(OH)_2(aq) \rightarrow Ca(s) + Mg(OH)_2(aq)[/tex] reaction will not occur as written.