Energy stored between the plates of capacitor is given by
[tex]U = \frac{1}{2}CV^2[/tex]
now we know that
voltage across the plates of capacitor is doubled
[tex]V' = 2V[/tex]
now the energy of the capacitor will be given as
[tex]U' = \frac{1}{2}C(2V)^2[/tex]
[tex]U' = 4(\frac{1}{2}CV^2)[/tex]
so here the energy stored between the plates of capacitor will becomes 4 times more