Yes, one can force the atoms into new configurations by pushing the atoms around, however, it will stay in a different conformation. It will adopt the geometry of lowest energy. The configurations of atoms in real molecules are flexible, however, they spend in the predicted geometries, for the majority of the time.
By forcing the atoms into a new configuration is possible.
The addition of new atoms around the atom will change the electronic geometry of the atoms. The addition of electron-accepting or donating atoms will result in a change in configuration. The configuration change will result in the change in the hybridization of the atom, and it will acquire a new shape. The geometry of the molecule changes and it will acquire the lowest energy state.
This suggests that atoms in real molecules are present in the flexible state of configuration, and are at least energy, The change in the surrounding changes the configuration of the atoms, and are easily configured.
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