Given the population of city = 150,000 people
Volume of water consumed by each person = 660.0 L
Total volume consumed in the city every year = [tex]150,000 persons * \frac{660.0L}{1 person*1day} [/tex]*[tex]\frac{365 days}{1 yr}[/tex]=[tex]3.61*10^{10}L[/tex]/year
The required fluoride concentration is 1.0 ppm
1.0 ppm means 1.0 mg fluoride per liter of water
Calculating the mass of NaF that must be added in kg:
[tex]3.61*10^{10} L/year*\frac{1 mg F^{-} }{1 L}*\frac{1g}{1000mg}*\frac{1molF^{-} }{19.00g}*\frac{1 mol NaF}{1 mol F^{-}}*\frac{42g}{1molNaF}*\frac{1kg}{1000g}[/tex]
= [tex]8.0 * 10^{4} kg NaF/year[/tex]