The concentration of the alkane c20h42 (fm 282.56) in a particular sample of rainwater is 0.2 ppb. assume that the density of rainwater is close to 1.00 g/ml and find the molar concentration of c20h42.

Respuesta :

Formula used for determining the molarity is:

[tex]Molarity = \frac{number of moles of solute}{volume of solution in Liters)}[/tex]  -(1)

Number of moles of solute that is [tex]C_{20}H_{42}[/tex] is determined as:

[tex]number of moles = \frac{given weight}{Molar mass}[/tex]  -(2)

Mass of the solute can be calculated as:

[tex]Density = \frac{mass}{volume}[/tex]

[tex]mass = density\times volume[/tex] - (3)

density of rain water = 1.00 g/mL (given)

Concentration of [tex]C_{20}H_{42}[/tex] = 0.2 ppb (given)

Since, [tex]1 ppb =[/tex] [tex]10^{-3} mg/L[/tex]

So, 0.2 ppb = [tex]0.2\times 10^{-3} mg/L = 2\times 10^{-4} mg/L[/tex]

Substituting the values in formula (3):

Mass = [tex]2\times 10^{-4} mg = 2\times 10^{-7} g[/tex]      (As 1 mg = [tex]10^{-3}[/tex] g).

Now, substituting the values of mass and formula mass in formula (2):

Number of moles = [tex]\frac{2\times 10^{-7}}{282.56} = 7.078\times 10^{-10} mole[/tex]

Volume of solution = 1 L

Substituting the values of number of moles and volume of solution in formula (1):

Molarity = [tex]\frac{7.078\times 10^{-10} mole}{1 L} = 7.078\times 10^{-10} M[/tex]

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