To solve this question we will use two important formulas.
The first formula involves the calculation of the decay constant, [tex] k [/tex] which is to be found as:
[tex] k=\frac{0.6931}{T_{\frac{1}{2}}} [/tex]
where [tex] T_{\frac{1}{2}} [/tex] is the half life of Pb-210 which is given to be 22 years in the question.
Thus, [tex] k=\frac{0.6931}{22}\approx0.0315 [/tex]
Now, we will use the second formula which is called the function of decay formula and is given as:
[tex] N = N_{0} e^{-kt} [/tex]
where [tex] N [/tex] percentage of Pb-210 remaining in the bone at present, which in our case is 67% or 0.67
[tex] N_{0} [/tex] percentage of Pb-210 to start with, which is always 100% or 1.
Plugging in all these values in the decay formula we are supposed to find the time, [tex] t [/tex].
[tex] 0.67=1\times e^{-0.0315t} [/tex]
Taking natural log on both sides we get:
[tex] ln(0.67)=-0.0315t [/tex]
[tex] \approx-0.4005=-0.0315t [/tex]
[tex] \therefore t=\frac{0.4005}{0.0315} [/tex]
[tex] t\approx12.71 [/tex] years
Therefore the bone fragment is about 12.71 years old.