The given chemical equation is,
[tex] 2NaHCO_{3}(aq) <---> Na_{2}CO_{3}(aq)+CO_{2}(g) + H_{2}O(g)[/tex]
When sodium carbonate is added the system tries to minimize the effect of the additional product added, by shifting the equilibrium such that the extra product is converted back to the reactants. This takes place until the equilibrium is re-established. Therefore, the equilibrium shifts towards the reactants side. The concentrations of sodium carbonate, carbon dioxide and water vapor decrease while the concentration of sodium hydrogen carbonate increases.