In this kind of exercises, you should use the "ideal gas" rules: PV = nRT
P should be in Pascal:
445mmHg = 59328Pa
1225mmHg = 163319Pa
V should be in cubic meter:
16L = 0.016 m3
R = [tex] \frac{PV}{nT} [/tex] = constant
[tex] \frac{P1 V1}{n T} [/tex] = [tex] \frac{P2 V2}{n T} [/tex]
==> P1 * V1 = P2 * V2
V2 = [tex] \frac{P1 V1}{P2} [/tex] = [tex] \frac{445 0.016}{1225} [/tex]
V2 = 0.00581 m3 = 5.81 L