6. The emission of brown fumes in the given experimental set-up is due to Brown fumes Lead nitrate -Burner (a) thermal decomposition of lead nitrate which produces brown fumes of nitrogen dioxide. (b) thermal decomposition of lead nitrate which produces brown fumes of lead oxide. (c) oxidation of lead nitrate forming lead oxide and nitrogen dioxide. (d) oxidation of lead nitrate forming lead oxide and oxygen. 1 ​