Basically the term which we use to refer them is lone pair. In Lewis structure why we represent those unbonded electron in pairs. Like here (structure of SO2)

Here if we assume both the unbonded electrons to be existing in pairs then it's geometry will be different from what we would observe in case when both electrons exists freely (without pair).
So why we basically consider those electrons to be existing in pair? Is it any kind of observation or any theory or both?